PFC is the prospective fault current. I.e. this is the highest current that can be expected to flow in the case of any fault in the circuit. It is the highest value obtained from the PSCC or the PEFC.
PSCC is the prospective short circuit current. I.e. this is the highest current that can be expected to flow in the case of a short between a line conductor and the neutral conductor or between two line conductors.
There is also PEFC, prospective earth fault current, this is the highest current that can be expected to flow in the case of a fault from a live conductor to earth.
These are not normally calculated but measured using a test meter.
You can calculate PEFC using the earth fault loop impedance measured with all bonding in place and the nominal voltage of the supply using ohms law.
PSCC in three phase systems is often calculated by measuring the phase to neutral fault current and multiplying by the rule of thumb value of 2, to give the likely (actually higher than it would be in reality) phase to phase short circuit current. This is where the meter cannot measure between phases directly.