Knob position needs to be sorted ASAP, then. That's why I said to mark the original position of the shaft.
Stored water temp. should be near enough the same whether heated by the immersion heater or the boiler. There's a thermostat under the cover of the immersion heater (electricity OFF), which may be marked in degrees, although they haven't been calibrated for many years. If it's an uncalibrated one it left the factory with the dial locked in place by a blob of sealant. Check for it having been 'got at', or it could just have gone wrong of course. if it has a calibrated dial, it should be set at 65 degrees.
The hot water temp, if the water is heated by the boiler, is set by the thermostat that can be seen strapped to the front of the cylinder. This should be set to 65 degrees as well. Can just make out the knob position in the pic, and it doesn't look far out.
The boiler flow temp. must be set slightly higher than the 'stat on the cylinder, otherwise the boiler will cycle on and off after the cylinder is 'full'. I suspect many boilers now suffer from this problem, following the misinformation put out by the government green brigade.