You might want to check the main fuse, as that is quite a lot of sub-mains coming off 3*100A for example, so if they turn out to be 160A or more then you have an easier job.
I had a go at the Schneider on-line tool but it seems broken for me today
I would concentrate on getting tolerable MCB/MCCB selectivity using the short-delay aspect of the fancy MCCB, that way in most cases the selectivity falls back to incoming fuse and final MCB, and that is probably no problem.
Yes, a sub-main fault might not open the MCCB before the incoming fuse, but that is a lot less likely than some final circuit/appliance giving them grief.
If you can find out loads and the PFC & PSCC at each DB just now it would help to decide how well the whole system would work.