Means even if the Zs value is higher than values mentioned in the BS7671 Table, the RCD will disconnect the earth fault . Am I wrong?
The RCD will disconnect quickly at impedances well above the Zs needed for the MCB, so in that sense you are right.
But equally if the Zs values is higher than what was designed (or reasonably expected for the type of circuit and size of installation) then it points to something going bad. Could be a loose joint, cable near the point of fracturing, bad repair with seriously under-spec cable, etc, which should be investigated.