No leakage clamp meter as yet, any recommendations?If the RCD is going at 19mA you've got very little overhead at all for 'normal' leakage. If you've a decent mA leakage clamp meter then now's the time to use it. If it were me I think I'd be looking to find ways of breaking that down into at least a couple of separate circuits and spreading the discrimination. You can always use a contactor to bring them back together again.
There is no N link between the boiler and the UFH as the wiring centres use a 0v built in relay to send the demand signal.
The remote Grundfos pumps and 2 port valves are controlled by the boiler spur, so I could separate the UFH and the boiler to 2 RCBOs